There are a number of Portuguese volunteer notaries that are available support incoming Ukrainian refugees. You can get free help at:
To operate in Portugal, you will be required to have certain identification numbers, even before you get your residence card, namely:
You can get these at a “Loja do Cidadão” (Citizen Store), a place that congregates several of the government services that exists almost in every Portuguese city.
Ukraine and the EU have signed an agreement on road freight transport, also known as "visa-free travel". What does it give?
The agreement eliminates the need for Ukrainian carriers to obtain permits for bilateral and transit traffic to EU countries and avoids stopping the export of Ukrainian products through road checkpoints;
provides for measures to facilitate the recognition of driver's licenses - now Ukraine and the EU exempt holders of driver's licenses issued by one of the parties from the requirement to have an international driver's license.
The term of the agreement is one year. It will earn on a permanent basis after the completion of all ratification procedures